勤益科大機構典藏:Item 987654321/1985
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    請使用永久網址來引用或連結此文件: http://ir.lib.ncut.edu.tw/handle/987654321/1985


    題名: 乙醇－水混合液透過HTPB-H12MDI之PU膜的研究
    作者: 黃世梁
    貢獻者: 化學工程系
    Department of Chemical Engineering
    關鍵詞: 羥基端聚丁二烯;聚胺基甲酸酯;氫鍵指數;FTIR;滲透蒸發;side-by-side cell
    日期: 1996-02
    上傳時間: 2008-12-05 10:26:35 (UTC+8)
    出版者: 勤益科技大學
    摘要: 以非極性羥基端聚丁二烯(Hydroxyl terminated polybutadiene, HTPB)聚合成之聚胺基甲酸酯(polyurethane, PU)聚合物。藉由滲透蒸發與side-by-side cell測試乙醇-水混合液透過PU膜的性質。硬質段含量的增加對乙醇-水混合液透過率的提高有所助益，但選擇比或乙醇、水透過的比值則有些微變值(frequency difference)作為吸附現象或選擇比大小探討的指標。這些數值乃藉由FTIR或FTIR-ATR的吸收強度測得。
    PU membranes were prepared by the nonpolar hydroxyl terminated polybutadiene with 4，4’-dicyclohexylmethane diisocyanate (H12MDI) and 1，4-butanediol (1，4-BD). The permeability of water-ethanol mixture increases with the increare of hard segment content of PU membrane. But their selectivity remains nearly constant or only slight increase. Hydrogen bonding index (HBI) and frequency difference by FTIR or FTIR-ATR as a measure of the average strength of the interpolymer hydrogen bonds were utilized to study the sorption phenomenon and permselectivity of the prepared membrane. The ethanol-water mixture permeate through membranes were studied by the pervaporation and side-by-side cell operaton.
    關聯: 勤益學報 No.13 p.127-139
    顯示於類別:[勤益科技大學] 勤益學報

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