Smart Technology for Evaluating Fire Extinguishing Effect of tert-Butyl Hydroperoxide

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Title:	Smart Technology for Evaluating Fire Extinguishing Effect of tert-Butyl Hydroperoxide
Authors:	李國義
Contributors:	工業工程與(工程)管理系
Date:	2013-08
Issue Date:	2017-09-30 13:00:28 (UTC+8)
Abstract:	tert-Butyl hydroperoxide (TBHP, 70 mass %), which is a solution of liquid peroxide, has been widely employed in the chemical industry as a polymerization initiator. The smart technology for predicting the mechanism of thermal decomposition and the inhibitive or hazardous reaction of TBHP by different calorimetric tests involves using differential scanning calorimetry (DSC) nonisothermal tests versus DSC isothermal tests and vent sizing package 2 (VSP2) adiabatic tests versus DSC nonisothermal tests, respectively, for further understanding how to extinguish organic peroxide accidents under fire scenario or runaway reaction in a chemical plant. Meanwhile, TBHP mixed with inhibitive and hazardous materials, such as various protic acids to help prevent runaway reactions, was applied on fires or explosions in the fire system. The results could be available to fire-related agencies as a reference application. The fire extinguishing system must be well-designed to decrease the degree of hazard. © 2013 American Chemical Society. (20 refs)
Relation:	INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Appears in Collections:	[Development of Industrial Engineering and Management] 【工業工程與管理系所】期刊論文

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